Model-Based Optimization of Semibatch Emulsion Polymerization of Styrene

نویسندگان
چکیده

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

Kinetics of styrene emulsion polymerization in the presence of montmorillonite

The effect of the pristine sodium montmorillonite (Na-MMT) on the styrene emulsion polymerizations with different concentrations of SDS ([SDS]) was investigated. At constant [SDS], the polymerization rate is faster for the run with 1 wt.% Na-MMT compared to the counterpart without Na-MMT. Micelle nucleation predominates in the polymerizations with [SDS] = 13 mM. On the other hand, the contribut...

متن کامل

Pickering Emulsion Polymerization of Styrene-co-butyl Acrylate Nanoparticles by Using Cloisite Na+ as Surfactant

Cloisite Na+was used as a solid surfactant (stabilizer) in Pickering emulsion polymerization of styrene-co-butyl acrylate in presence of oil soluble initiator, azobisisobutyronitrile (AIBN) and water soluble initiator, potassium persulfate (KPS). Fourier transform infrared (FTIR) spectrum approved the corporation of Cloisite Na+ layers within the polymer matrix. Effect of clay content was a...

متن کامل

Optimal Temperature Control of Semibatch Polymerization Reactors

B Abstract. Recently, in a paper of Chylla and Haase 2], a model of a multi-product semibatch polymerization reactor has been developed which is representative of those found in the speciality chemical processing industry. One of the aims in these processes is to keep a certain reaction temperature setpoint, in order to t the quality requirements for the polymer. In the present paper, the optim...

متن کامل

Experimental data in support of continuous microwave effect on emulsion polymerization of styrene

This article contains original experimental data, figures and methods to the study of Microwave-assisted emulsion polymerization of styrene under the frame of "Enhanced Microwave Synthesis" (EMS), has been examined to investigate the advantages of Microwave (MW) power use in emulsion polymerization (Ergan et al., Eur. Polym. J. 69, 2015, 374-384). For comparative purpose, MW and conventional he...

متن کامل

Run-to-run Optimization of Batch Emulsion Polymerization

Run-to-run optimization exploits the repetitive nature of batch processes to adapt the operating policy in the presence of uncertainty. For problems where terminal constraints play a dominant role in the optimization, the system can be operated close to the optimum simply by satisfying terminal constraints. The input is parameterized by using the knowledge of the shape of the optimal solution a...

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Industrial & Engineering Chemistry Research

سال: 2020

ISSN: 0888-5885,1520-5045

DOI: 10.1021/acs.iecr.0c02771